Na Pali Coast. By boat, by helicopter, or on the Kalalau trail. There is no road, so seeing it takes a decision and a booking.
Waimea Canyon. Signposted as the Grand Canyon of the Pacific, and unlike most such nicknames it earns it. Go in the morning before cloud builds.
Hanalei Bay. A two mile crescent on the north shore, with the pier and the mountains behind it. The image most people have of Kauai.
Helicopter over the interior. Most of Kauai cannot be reached by road at all. This is the only way to see the middle of the island.
Poipu and the south shore beaches. Reliable sun, snorkeling, and monk seals that haul out on the sand and get their own roped off area.
Wailua River and the waterfalls. Kayaking, and the falls on the east side, which are at their best right after rain.